A novel approach for new cost-saving durable anticorrosive and antibacterial coatings
Autor: | Eglal R. Souaya, Nivin M. Ahmed, Walaa M. Abd El-Gawad, Wael S. Mohamed |
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Rok vydání: | 2019 |
Předmět: |
Nanocomposite
Materials science Diffusion Emulsion polymerization 02 engineering and technology Surfaces and Interfaces General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Surfaces Coatings and Films Cost savings Dielectric spectroscopy Colloid and Surface Chemistry Chemical engineering Copolymer 0210 nano-technology |
Zdroj: | Journal of Coatings Technology and Research. 16:1263-1281 |
ISSN: | 1935-3804 1547-0091 |
DOI: | 10.1007/s11998-019-00202-9 |
Popis: | Multifunctional coatings that perform various actions simultaneously are now of prevailing importance, with zeolites being one of the most useful materials in this field. In this work, Na-P-zeolite was prepared from kaolin and subjected to a cation-exchange process to replace Na+ by Cu2+ and/or Zn2+ to achieve anticorrosive and antibacterial effects. In situ emulsion polymerization of vinyl acetate-vinyl versatate (VAc-VEOVA) copolymer at the nanoscale with P-zeolite and Zn-, Cu-, Zn/Cu-cation-exchanged P-zeolites was then applied to obtain P-zeolite-(VAc-VEOVA), Zn-P-zeolite-(VAc-VEOVA), Cu-P-zeolite-(VAc-VEOVA), and Zn/Cu-P-zeolite-(VAc-VEOVA) nanocomposites. Anticorrosive and antibacterial tests were then carried out on films containing the different nanocomposites using laboratory accelerated testing, electrochemical impedance spectroscopy (EIS), and the disc well diffusion method with different types of Gram-positive (G+) and Gram-negative (G−) bacteria, revealing that the film containing the mixed (Zn/Cu)-P-zeolite showed the best anticorrosive and antibacterial performance. |
Databáze: | OpenAIRE |
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