Cp2ZrCl2-Catalyzed cycloalumination of acetylenic alcohols and propargylamines by Et3Al

Autor:	Ilfir Ramazanov, Lilya Dzhemileva, Rita Kadikova, Usein Dzhemilev
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Hydrolysis chemistry.chemical_compound chemistry Yield (chemistry) Propargyl Organic chemistry Regioselectivity Stereoselectivity General Chemistry Alkyl Allylamine Catalysis
Zdroj:	Russian Chemical Bulletin. 60:99-106
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-011-0013-2
Popis:	The Cp2ZrCl2-catalyzed cycloalumination of acetylenic alcohols and propargylamines by Et3Al was studied. The process affords 2,3-disubstituted alumacyclopent-2-enes, which were identified by the analysis of the products of their deuterolysis and hydrolysis. The cycloalumination of alkyl- and phenyl-substituted propargylamines proceeds with high regio- and stereoselectivity to give the corresponding allylamine derivatives in high yield. Unlike the phenyl derivatives, the cycloalumination of alkyl-substituted acetylenic alcohols (propargyl, homopropargyl, and bishomopropargyl alcohols) is not regioselective.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e092e8e49d4260cb4caefde3ab611c1 https://doi.org/10.1007/s11172-011-0013-2 Zobrazit plný text záznamu Full text from SpringerLink