Scavenging Effects of Aliphatic Alcohols and Acetone on H• Radicals in Anodic Contact Glow Discharge Electrolysis: Determination of the Primary Yield of H• Radicals

Autor:	Urvashi Gangal, Monika Srivastava, Susanta K. Sen Gupta
Rok vydání:	2010
Předmět:	Glow discharge Electrolysis Primary (chemistry) General Chemical Engineering Radical General Chemistry Condensed Matter Physics Photochemistry Surfaces Coatings and Films Anode law.invention chemistry.chemical_compound chemistry law Yield (chemistry) Acetone Scavenging
Zdroj:	Plasma Chemistry and Plasma Processing. 30:299-309
ISSN:	1572-8986 0272-4324
Popis:	A study of scavenging effects of iso-propanol, n-propanol, n-butanol and acetone on H• radicals, precursors for nonfaradaic products of anodic contact glow discharge electrolysis (CGDE) in aqueous media, has been carried out. A kinetic analysis of the competing reactions of H• with different species in the system leads to a primary yield of 9.8 mol (mol electron)−1 each of H• and OH• radicals in the liquid-phase reaction zone of anodic CGDE. The method is considerably more convenient to apply than those reported earlier based on the use of OH• scavengers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e0725e2151af02112a8308542a0e583 https://doi.org/10.1007/s11090-010-9216-9 Zobrazit plný text záznamu Full text from SpringerLink