ChemInform Abstract: Novel Synthesis of Fused Indoles and 2-Substituted Indoles by the Palladium-Catalyzed Cyclization of N-Cycloalkenyl-o-haloanilines

Autor:	Hiromichi Yamashita, Takeshi Watanabe, Shigeru Arai, Atsushi Nishida, Jun Maruyama
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Double bond chemistry Condensation Organic chemistry chemistry.chemical_element General Medicine Isomerization Combinatorial chemistry Catalysis Palladium
Zdroj:	ChemInform. 40
ISSN:	1522-2667 0931-7597
Popis:	A new palladium-catalyzed cyclization of N-alkenyl-o-haloanilines with selective isomerization of a double bond followed by formal 5-endo-trig cyclization was developed. A variety of fused and 2-substituted indoles were synthesized from enaminoesters prepared by condensation of β-ketoesters and o-iodoaniline.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3de646700f2591b494a5b3017e8ba6de https://doi.org/10.1002/chin.200923119 Zobrazit plný text záznamu Plný text