Improved Dimerization of Diethyl Acetonedicarboxylate Leading to Polyfunctionalized Phenol

Autor:	Nagatoshi Nishiwaki, Mina Tamura, Hajime Yagi, Makoto Matsumoto, Takanobu Shinkawa, Masahiro Ariga
Rok vydání:	2005
Předmět:	chemistry.chemical_compound Nitrophenol chemistry General Chemical Engineering Sodium Yield (chemistry) Pyridine chemistry.chemical_element Organic chemistry Phenol General Medicine General Chemistry
Zdroj:	Journal of Oleo Science. 54:461-464
ISSN:	1347-3352 1345-8957
Popis:	When a pyridine solution of sodium enolate of diethyl acetonedicarboxylate was heated in the presence of p-nitrophenol, the dimerization readily proceeded under mild conditions to give polyfunctionalized phenol, ethyl {2,4-bis(ethoxycarbonyl)-3,5-dihydroxyphenyl}acetate, in moderate yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3de1496920c845cb370b4730adcdd0d0 https://doi.org/10.5650/jos.54.461 Zobrazit plný text záznamu