Synthesis, Structure, and Luminescent Property of One Zinc(II) Coordination Polymer Constructed From 1H-Benzoimidazole

Autor:	Shu-Hua Zhang, Hai Yang Zhang, Gui Li, Ru Xia Zhao, Heping Li
Rok vydání:	2016
Předmět:	Denticity 010405 organic chemistry Ligand Coordination polymer Stereochemistry chemistry.chemical_element Zinc Crystal structure 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Elemental analysis Physical and Theoretical Chemistry Luminescence Monoclinic crystal system
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 46:804-808
ISSN:	1553-3182 1553-3174
DOI:	10.1080/15533174.2014.989593
Popis:	A new metal-organic coordination polymer [Zn(bm)(AcO)]n (1), where Hbm is 1H-benzoimidazole), has been prepared and structurally characterized by IR, elemental analysis and single-crystal X-ray diffraction. Single-crystal X-ray analysis shows that it crystallizes in the monoclinic space group of P21/c with a = 10.8231(5) A, b = 9.8329(4) A, c = 8.8665(4) A, β = 99.298(4)°, V = 931.20(7) A3, and Z = 4. The bm ligand bridges two adjacent Zn(II) with its two nitrogen atoms to form a one-dimensional chain, which further constructed 2D network through a bridge bidentate AcO− ligand. Furthermore, luminescent property of 1 was investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3dd9447488e78ca94df39b85ec76b36c https://doi.org/10.1080/15533174.2014.989593 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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