MEL Zeolites: Synthesis, Properties, and Catalytic Applications
| Autor: | Irina I. Ivanova, Elena E. Knyazeva, V. A. Vorobkalo |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Isobutylene
010405 organic chemistry Chemistry General Chemical Engineering Energy Engineering and Power Technology General Chemistry Alkylation 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis law.invention Crystal chemistry.chemical_compound Fuel Technology Chemical engineering Nanocrystal Geochemistry and Petrology law hemic and lymphatic diseases Crystallization Zeolite Amination |
| Zdroj: | Petroleum Chemistry. 61:299-324 |
| ISSN: | 1555-6239 0965-5441 |
| DOI: | 10.1134/s0965544121030099 |
| Popis: | The review provides an analysis of the synthesis design features and the acidic and catalytic properties of MEL-type zeolites. Practicable methods for MEL zeolite synthesis are discussed, including one-step and two-step implementations of hydrothermal crystallization, crystal seed assisted synthesis, dual template synthesis, and vapor-phase crystallization to obtain nanocrystalline zeolites as isolated nanocrystals or binderless pellets. The study also provides an overview of methods for targeted control of the phase purity, chemical composition, crystal morphology/size, and acidic properties of MEL zeolite. Relationships are demonstrated between the MEL synthesis conditions and the catalytic properties of these zeolites in alkylation and disproportionation of aromatic compounds, oligomerization of lower olefins, oxidation of glycerol, amination of isobutylene, and conversion of lower alcohols. |
| Databáze: | OpenAIRE |
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