Co-cross-linking of bio-based multi-functional epoxide and bisphenol A diglycidyl ether with 2-ethyl-4-methylimidazole
| Autor: | Hisatoyo Morinaga, Mayu Sakamoto |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Thermal decomposition Epoxide Bio based 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry 0104 chemical sciences Adhesion strength chemistry.chemical_compound chemistry Limonene oxide Drug Discovery Copolymer 4-Methylimidazole Organic chemistry 0210 nano-technology Bisphenol A diglycidyl ether |
| Zdroj: | Tetrahedron Letters. 59:3889-3891 |
| ISSN: | 0040-4039 |
| Popis: | A co-cross-linking reaction of bio-based multi-functional epoxides (1) derived from limonene oxide and bisphenol A diglycidyl ether (BPADE) in the presence of 2-ethyl-4-methylimidazole (EMI) as a cross-linker afforded the corresponding network copolymers (2) having the 10% thermal decomposition temperature (Td10) of 294.4 °C at maximum. Adhesive strength induced by 1, especially tetra-functional epoxide, and BPADE exhibited remarkably higher than that by BPADE alone. |
| Databáze: | OpenAIRE |
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