Synthesis and spectral properties of ruthenium(II) complexes based on 2,2′-bipyridines modified by a perylene chromophore

Autor:	Koichi Kodama, Takuji Hirose, Akinori Kobayashi
Rok vydání:	2013
Předmět:	Absorption spectroscopy Chemistry Ligand Organic Chemistry chemistry.chemical_element Chromophore Conjugated system Photochemistry Biochemistry 2 2'-Bipyridine Ruthenium chemistry.chemical_compound Drug Discovery Polymer chemistry Moiety Perylene
Zdroj:	Tetrahedron Letters. 54:5514-5517
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2013.07.150
Popis:	Five new 2,2′-bipyridines functionalized with a perylene or a perylenediimide moiety were synthesized and the corresponding heteroleptic ruthenium(II) complexes ([Ru(bpy) 2 ( L )](PF 6 ) 2 ; bpy = 2,2′-bipyridyl, L = perylene-substituted bpy ligand) were prepared. The UV–vis spectra of the ruthenium(II) complexes showed red-shifted and intense absorption bands derived from the conjugated structure of the new ligands.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3d9c15c5d2f217664974e989676fb6a3 https://doi.org/10.1016/j.tetlet.2013.07.150 Zobrazit plný text záznamu Full Text from ScienceDirect