REDUCTION OF STEROIDS USING LITHIUM ALUMINUM HYDRIDE
Autor: | Gordon A. Grant, Edwin M. Richardson, Gilles Papineau-Couture |
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Rok vydání: | 1949 |
Předmět: | |
Zdroj: | Canadian Journal of Research. :902-906 |
ISSN: | 1923-4287 |
Popis: | Lithium aluminum hydride has been used successfully in the partial reduction of phthalic anhydride to phthalide, in the selective reduction of the carbonyl group of dehydroisoandrosterone-3-acetate, and in the reduction of oestrone acetate to α-oestradiol without simultaneous production of the β-isomer. A new reduction product of Δ5-3(β)hydroxyetiobilienic acid, Δ9,14-2,13-dimethyl-7(β)hydroxy-2-hydroxymethyl-1-hydroxyethyl dodecahydrophenanthrene, is also described. |
Databáze: | OpenAIRE |
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