Open metal sites dangled on cobalt trigonal prismatic clusters within porous MOF for CO2 capture

Autor:	Yu-Sheng Chen, Wen-Yang Gao, Shengqian Ma, Sathvik Palakurty, Lukasz Wojtas
Rok vydání:	2015
Předmět:	Functional role Materials science Ligand Inorganic chemistry chemistry.chemical_element Trigonal prismatic molecular geometry Inorganic Chemistry Metal chemistry.chemical_compound Crystallography chemistry visual_art visual_art.visual_art_medium Pyrene SBus Porosity Cobalt
Zdroj:	Inorganic Chemistry Frontiers. 2:369-372
ISSN:	2052-1553
Popis:	Open metal sites are devised to dangle on cobalt trigonal prismatic secondary building units (SBUs) of a porous MOF, when a rigid octacarboxylate ligand, 1,3,6,8-tetra(3,5-dicarboxylphenyl)pyrene, assembled with Co(NO3)2 under solvothermal conditions. The functional role of dangled open metal sites is exploited for CO2 capture studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3d65f4d03509466e66419c2139e7e959 https://doi.org/10.1039/c4qi00240g Zobrazit plný text záznamu