Unexpectedly Small Effect of the DNA Environment on Vertical Ionization Energies of Aqueous Nucleobases
| Autor: | Pavel Jungwirth, Eva Pluhařová, Stephen E. Bradforth, Petr Slavíček, Bernd Winter, Christi Schroeder, Robert Seidel, Manfred Faubel |
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| Rok vydání: | 2013 |
| Předmět: |
Physics::Biological Physics
Quantitative Biology::Biomolecules Aqueous solution Chemistry Solvation Nucleobase chemistry.chemical_compound X-ray photoelectron spectroscopy Ab initio quantum chemistry methods Computational chemistry Physics::Atomic and Molecular Clusters General Materials Science Physics::Atomic Physics Physical and Theoretical Chemistry Ionization energy DNA |
| Zdroj: | The Journal of Physical Chemistry Letters. 4:3766-3769 |
| ISSN: | 1948-7185 |
| DOI: | 10.1021/jz402106h |
| Popis: | By a combination of ab initio calculations and photoelectron spectroscopy, we demonstrate that the DNA surrounding has only a negligible effect on ionization energies of nucleobases in the native a... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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