Aggregation of carbamato ligands around the [Co4O]6+ core. Synthesis and structure of the cluster [Co4O(O2CNC9H18)6] prepared by a novel oxo-transfer reaction of the nitroxyl free radical 2,2,6,6-tetramethylpiperidin-1-oxyl with [Co2(CO)8]
| Autor: | Peter Jaitner, Klaus Wurst, Christopher Rieker |
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| Rok vydání: | 1997 |
| Předmět: |
Metals and Alloys
chemistry.chemical_element Nitroxyl General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Yield (chemistry) Polymer chemistry Materials Chemistry Ceramics and Composites Cluster (physics) Molecule Organic chemistry Cobalt |
| Zdroj: | Chemical Communications. :1245-1246 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/a701238a |
| Popis: | The novel oxo-centred tetrahedral cobalt cluster [Co 4 O] 6+ bridged by six carbamato ligands is prepared in high yield when reacting [Co 2 (CO) 8 ] with an excess of the nitroxyl radical 2,2,6,6-tetramethylpiperidin-1-oxyl; the molecular structure of the title compound is determined by a single-crystal X-ray analysis. |
| Databáze: | OpenAIRE |
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