Synthesis of a New Spiro System: 1-Oxa-7-thia-4-azaspiro[4.5]decane 7,7-Dioxide

Autor: S. Yu. Mykolenko, Alexandr A. Gaponov, Roman M. Chabanenko, Vitaliy A. Palchikov
Rok vydání: 2018
Předmět:
Zdroj: Russian Journal of Organic Chemistry. 54:588-592
ISSN: 1608-3393
1070-4280
Popis: Dihydro-2H-1λ6-thiopyran-1,1,3(4H)-trione reacted with N-substituted 2-aminoethanols to give derivatives of a new spiro system, 1-oxa-7λ6-thia-4-azaspiro[4.5]decane-7,7-diones. No spirocyclic product was obtained by the reaction with unsubstituted 2-aminoethanol, but the corresponding enamine was formed as in the reactions with other primary amines.
Databáze: OpenAIRE