Photochemical interaction of phosphine hydride complexes of molybdenum and tungsten with carbon monoxide

Autor:	Yu. V. Gak, A. P. Pivovarov, L. M. Ioffe, A. P. Borisov, Viktor D. Makhaev
Rok vydání:	1983
Předmět:	Chemistry Ligand Hydride Inorganic chemistry chemistry.chemical_element General Chemistry Tungsten Photochemistry Metal chemistry.chemical_compound Metal carbonyl hydride Molybdenum visual_art visual_art.visual_art_medium Phosphine Carbon monoxide
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:1163-1167
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00953149
Popis:	Irradiation of phosphine hydride complexes MH4L4, where M=Mo or W and L=PMePh2 or 1/2(Ph2PCH2)2, in a CO atmosphere leads to successive replacement of the hydride and phosphine ligands by carbonyl, forming M(CO)xL6−x (x=2, 3, 4, 5). The degree of substitution x depends on the nature of the metal M and ligand L and on the length of the irradiation period. The rate of photochemical interaction of MH4L4, with CO is approximately two orders of magnitude greater than the rate of the analogous dark reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3d2e88a11a29a24b5b732e1ff1342e30 https://doi.org/10.1007/bf00953149 Zobrazit plný text záznamu Full text from SpringerLink