Group IV organometallic sulfur compounds
| Autor: | Wenzel E. Davidson, Malcolm C. Henry, Kenneth Hills |
|---|---|
| Rok vydání: | 1965 |
| Předmět: |
Organic base
Organic Chemistry Thio Halide chemistry.chemical_element Ethanedithiol Ring (chemistry) Biochemistry Medicinal chemistry Sulfur Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Materials Chemistry visual_art.visual_art_medium Organic chemistry Thioglycolic acid Physical and Theoretical Chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 3:285-294 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)84648-3 |
| Popis: | A number of thio derivatives of the types (C 6 H 5 ) 2 MSR and (C 6 H 5 ) 2 M(SR) 2 , M = Ge, Sn or Pb, have been synthesized by reactions of thiols with the triphenyl- or diphenyl-metal halides in the presence of a tertiary organic base. The thermal and hydrolytic stabilities of these compounds are discussed. Heterocyclic derivatives with metal atoms in the ring were isolated from reactions of the dihalodiphenylmetal compounds with ethanedithiol, thioglycolic acid and 2-hydroxyethanethiol. |
| Databáze: | OpenAIRE |
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