Radical reactions on furanoside acetals: A formal synthesis of (−)-canadensolide from D-mannose

Autor:	G. V. M. Sharma, S. Mahender Rao, K. Krishnudu
Rok vydání:	1995
Předmět:	chemistry.chemical_classification Bicyclic molecule Glycal Stereochemistry Organic Chemistry Synthon Mannose Catalysis Inorganic Chemistry Formal synthesis chemistry.chemical_compound chemistry Intramolecular force Physical and Theoretical Chemistry Derivative (chemistry) Octane
Zdroj:	Tetrahedron: Asymmetry. 6:543-548
ISSN:	0957-4166
DOI:	10.1016/0957-4166(95)00038-q
Popis:	By adaption of an intramolecular radical cyclisation protocol to the furanoid glycal derivative 3 derived from D-mannose, synthesis of the crucial bicyclo[3.3.0]octane system 6 is reported. A sequence of reactions on this key synthon 6, leading to the formal synthesis of (−)-canadensolide (1) is described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3d1a2ab2d88f4396f7c1a324a972ac97 https://doi.org/10.1016/0957-4166(95)00038-q Zobrazit plný text záznamu Full Text from ScienceDirect