Application of electrogenerated triphenylmethyl anion as a base for alkylation of arylacetic esters and arylacetonitriles and isomerization of allylbenzenes

Autor:	Mitsuko Kato, Shohei Suzuki, Shoichi Nakajima
Rok vydání:	1994
Předmět:	chemistry.chemical_classification Nitrile Base (chemistry) Chemistry Organic Chemistry Halide General Chemistry Alkylation Electrochemistry Medicinal chemistry Catalysis Ion chemistry.chemical_compound Isomerization Alkyl
Zdroj:	Canadian Journal of Chemistry. 72:357-361
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v94-055
Popis:	Phenylacetic esters and phenylacetonitriles were alkylated with alkyl halides, at the position α to an ester or nitrile, either at room temperature (20 °C) or at −78 °C, by making use of electrogenerated triphenylmethyl anion (trityl anion). Double-bond isomerization of allylbenzenes was also effectively accomplished by use of this electrogenerated base (EGB).
Databáze:	OpenAIRE
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