Catalytic Conversion of Cellulose to 5-hydroxymethylfurfural (5-HMF) Over Nano SO42--ZrO2 /MCM-41 Catalysts

Autor:	Le Ha Giang, Pham Tung Son, Vu Anh Tuan, Nguyen Ba Manh, Vu Quang Loi, Le Thanh Son, Pham Thi Thu Trang
Rok vydání:	2020
Předmět:	chemistry.chemical_compound chemistry Chemical engineering MCM-41 5-hydroxymethylfurfural Nano Cellulose Catalysis
Zdroj:	VNU Journal of Science: Natural Sciences and Technology. 36
ISSN:	2588-1140 2615-9317
DOI:	10.25073/2588-1140/vnunst.4976
Popis:	A zirconium catalyst system supported on MCM-41 (S-Z) with various weight components (4-20 wt.%) Was synthesized by the sol-gel method. Structure and Morphology Catalysts were characterized by X-RD, TEM, BET, FT-IR and TPD-NH3 methods. In this catalyst, ZrO2 is highly dispersed on the surface of MCM-41 capillaries. Catalytic activity and selectivity were evaluated by the effectiveness of mild hydrothermal decomposition of cellulose to 5-hydroxymethyl furfural (5-HMF). The results show that a catalyst with medium acidity exhibits a high selectivity of 5-HMF. Keywords: S-Zr/MCM-41 materials, sol-gel methods, cellulose, 5-HMF.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3d083ba9ec33ed860a9d86ccd4c19d9b https://doi.org/10.25073/2588-1140/vnunst.4976 Zobrazit plný text záznamu