Synthesis and chemical properties of polyphenols with oligoaniline pendant groups

Autor:	Ami Suyama, Isao Yamaguchi, Kazuyuki Goto, Moriyuki Sato
Rok vydání:	2012
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Polymers and Plastics chemistry Polyphenol Yield (chemistry) Organic Chemistry Polymer chemistry Materials Chemistry Phenol Hydrazine monohydrate Oxidative coupling of methane Polymer
Zdroj:	High Performance Polymers. 24:366-372
ISSN:	1361-6412 0954-0083
Popis:	Horseradish peroxidaze (HRP)- or N, N′-bis(salicylidene)ethylenediamineiron(III)-catalyzed polymerizations of 4-(4-phenylaminophenylamino)phenol (monomer-1) and 4-[4-(4-phenylaminophenylamino)phenylamino]phenol (monomer-2) caused oxidative coupling at the hydroxyphenyl group to yield polyphenols (PPs) with pendant oligoaniline (OAN) groups. UV-vis measurements suggested that the OAN pendant groups of the polymers were oxidized in air, resulting in the formation of quinoid structures, which were converted into benzonoid structures by treatment with hydrazine monohydrate. The polymers were electrochemically oxidized in solution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3d05f43c6bf4cb57317d23f0085ff4f8 https://doi.org/10.1177/0954008312439081 Zobrazit plný text záznamu