In Situ Sulfidation of Pd/C: A Straightforward Method for Chemoselective Conjugate Reduction by Continuous Hydrogenation
| Autor: | Jonathan C. Moore, Gareth N. Jenkins, Michael W. George, Rowena A. Howie, Martyn Poliakoff, Samuel L. Bourne, Peter Licence |
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| Rok vydání: | 2019 |
| Předmět: |
In situ
Olefin fiber Materials science Renewable Energy Sustainability and the Environment Continuous flow General Chemical Engineering Sulfidation 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Reduction (complexity) Chemical engineering Scientific method Environmental Chemistry 0210 nano-technology Conjugate |
| Zdroj: | ACS Sustainable Chemistry & Engineering. 7:16814-16819 |
| ISSN: | 2168-0485 |
| Popis: | A method has been developed for the in situ sulfidation of Pd/C under continuous flow. The approach provides a cheap, sustainable, and operationally convenient method for chemoselective conjugate reduction by continuous hydrogenation. High conversions and excellent selectivities were obtained for olefin reduction in α/β-unsaturated carbonyl compounds in the presence of hydrogenatively sensitive functionalities. The methodology was analyzed with a green metric system to highlight the sustainability features of the process. |
| Databáze: | OpenAIRE |
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