Enantioselective radical allylation reactions using chiral lanthanide Lewis acids

Autor:	Shankar Manyem, Mukund P. Sibi, Rajesh Subramaniam
Rok vydání:	2003
Předmět:	Lanthanide Acrylate chemistry.chemical_compound chemistry Lanthanide trifluoromethanesulfonates Organic Chemistry Drug Discovery Polymer chemistry Enantioselective synthesis Lewis acids and bases Biochemistry Prolinol
Zdroj:	Tetrahedron. 59:10575-10580
ISSN:	0040-4020
DOI:	10.1016/j.tet.2003.07.019
Popis:	Radical additions to oxazolidinone acrylate followed by allyl trapping were studied with chiral Lewis acids derived from lanthanide salts. Chiral ligands were evaluated to establish the α-stereocenter. Ligands with a prolinol framework along with achiral additives proved to be effective. The observed trends are compared with those in the literature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3ce88556f262db2825e712c7c69d2646 https://doi.org/10.1016/j.tet.2003.07.019 Zobrazit plný text záznamu Full Text from ScienceDirect