One trinuclear copper(II) complex derived from a new Schiff base ligand based on the dianion of 4-chloro-6-(hydroxymethyl)-2-((3-aminopropylimino)methyl)-phenol: Synthesis, structure, spectroscopic and magnetic properties
| Autor: | Wei Huang, Zhaolian Chu, Juechao Jiang |
|---|---|
| Rok vydání: | 2009 |
| Předmět: |
Schiff base
Chemistry Ligand Stereochemistry chemistry.chemical_element Crystal structure Copper Magnetic susceptibility Square pyramidal molecular geometry Inorganic Chemistry Crystallography chemistry.chemical_compound Octahedron Materials Chemistry Hydroxymethyl Physical and Theoretical Chemistry |
| Zdroj: | Inorganica Chimica Acta. 362:2933-2936 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2008.11.018 |
| Popis: | A linear trinuclear copper(II) complex ( 1 ), prepared from a new Schiff base ligand, namely the dianion of 4-chloro-6-(hydroxymethyl)-2-((3-aminopropylimino)methyl)-phenol, was synthesized and characterized in this paper. The X-ray structural study reveals that the geometry of the central Cu2 ion is elongated octahedral and that of the two side Cu(II) ions is distorted square pyramidal. The magnetic susceptibility measurements from 2 to 300 K reveal medium antiferromagnetic interactions between the Cu(II) ions with a J value of −64.6(1) cm −1 . |
| Databáze: | OpenAIRE |
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