Glass-transition temperature and microstructure of polybutadienes

Autor:	E. V. Temnikova, N. Makhiyanov
Rok vydání:	2010
Předmět:	Materials science Polybutadiene Polymers and Plastics Materials Chemistry Composite material Microstructure Glass transition
Zdroj:	Polymer Science Series A. 52:1292-1300
ISSN:	1555-6107 0965-545X
DOI:	10.1134/s0965545x10120072
Popis:	DSC and NMR are employed to determine the glass-transition temperatures and the structural features of polybutadienes with widely varying configuration isomeric compositions. The dependences of the glass-transition temperature on the contents of cis-1,4-, trans-1,4, and 1,2-units in polybutadiene chains are plotted and discussed. An analysis of the experimental results and the published data suggests that, in the study of the glass-transition-structure relationship, simplified approaches are inapplicable and it is necessary to consider the configurational and conformational geometry of polybutadiene chains.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3cc2bfa1820b027840b03fea015430e9 https://doi.org/10.1134/s0965545x10120072 Zobrazit plný text záznamu Full text from SpringerLink