Metal complexes as donor ligands: Formation of metal—metal bonded species via intramolecular rearrangement
| Autor: | R.J. Haines, J. C. T. R. Burckett-St. Laurent, C.R. Nolte |
|---|---|
| Rok vydání: | 1976 |
| Předmět: |
Chemistry
Organic Chemistry chemistry.chemical_element Photochemistry Biochemistry Rhodium Inorganic Chemistry Metal chemistry.chemical_compound visual_art Intramolecular force Polymer chemistry Materials Chemistry visual_art.visual_art_medium Metal metal Physical and Theoretical Chemistry Carbon monoxide |
| Zdroj: | Journal of Organometallic Chemistry. 104:C27-C30 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)91682-6 |
| Popis: | The reactions of the metal-containing phosphines and sulphides, P(C 6 H 5 ) 2 MR and SR′MR [MR = Fe(CO) 2 (η 5 -C 5 H 5 ); R′ = C 2 H 5 , t-C 4 H 9 or C 6 H 5 ] with various rhodium(I) derivatives, are described; [Rh{FeP(C 6 H 5 ) 2 (CO) 2 η 5 -C 5 H 5 )} 2 ] + , which contains bridging as well as terminal carbonyls, reacts reversibly with carbon monoxide and weakly coordinating solvents to afford species containing terminal carbonyls only. |
| Databáze: | OpenAIRE |
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