Practical and efficient synthesis of perfluoroalkyl iodides from perfluoroalkyl chlorides via modified sulfinatodehalogenation

Autor:	Qing-Yun Chen, Hai-Ping Cao
Rok vydání:	2007
Předmět:	Inorganic Chemistry Sodium dithionite chemistry.chemical_compound chemistry Sodium Organic Chemistry One-pot synthesis Environmental Chemistry Organic chemistry chemistry.chemical_element Physical and Theoretical Chemistry Iodine Biochemistry
Zdroj:	Journal of Fluorine Chemistry. 128:1187-1190
ISSN:	0022-1139
DOI:	10.1016/j.jfluchem.2007.04.018
Popis:	A novel two-step one pot synthesis of perfluoroalkyl iodides (α,ω-diiodoperfluoroalkanes) from perfluoroalkyl chlorides (α-chloro-ω-iodoperfluoroalkanes) has been developed by initial conversion to the corresponding sodium perfluoroalkanesulfinates with sodium dithionite and then subsequent oxidation by iodine.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3c95ed0c570e3a5bc3e2c7831d7667de https://doi.org/10.1016/j.jfluchem.2007.04.018 Zobrazit plný text záznamu Full Text from ScienceDirect