Structure and reactivity studies of the aluminum analogue of Piers’ borane [HAl(C6F5)2]3

Autor: Jingjie Tan, Chaopeng Hu, Xin Yang, Shaoying Ju, Levy L. Cao, Yile Wu, Liu Leo Liu, Douglas W. Stephan
Rok vydání: 2023
Předmět:
Zdroj: Chemical Communications. 59:282-285
ISSN: 1364-548X
1359-7345
DOI: 10.1039/d2cc06075b
Popis: The aluminum analogue of Piers’ borane, [HAl(C6F5)2]3, is prepared on a gram-scale and shown to be highly acidic, a strong hydride donor, and a catalysts for the hydrosilylation of alkynes and alkenes.
Databáze: OpenAIRE