Reaction of 2-aza-1,3,5-trienes with superbases: an unexpected approach towards exomethylene tetrahydroazepines

Autor:	N. A. Nedolya, Ol'ga G. Volostnykh, Boris A. Trofimov, Ol'ga A. Tarasova, A. I. Albanov
Rok vydání:	2011
Předmět:	chemistry.chemical_compound Deprotonation chemistry Isothiocyanate Organic chemistry General Chemistry
Zdroj:	Russian Chemical Bulletin. 60:2617-2620
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-011-0402-6
Popis:	Reaction of 2-methoxy-N-(1-methylpropylidene)-1-(methylsulfanyl)buta-1,3-dien-1-amine with ButOK resulted in 2-ethylidene-6-methoxy-7-(methylsulfanyl)-3,4,5,6-tetrahy-dro-2H-azepine, the first example of 2-ethylidene-3,4,5,6-tetrahydro-2H-azepines, along with hitherto unknown 7-ethyl-3-methoxy-2-(methylsulfanyl)-4,5-dihydro-3H-azepine and 2-ethyl-6-methoxy-3H-azepine.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3c888dfa4ad9b8ac6d178ba97e0454f1 https://doi.org/10.1007/s11172-011-0402-6 Zobrazit plný text záznamu Full text from SpringerLink