Synergistic catalytic effect of Ti–B on the graphitization of polyacrylonitrile-based carbon fibers
Autor: | Weixin Yu, Fengying Zhang, Qingyun Cai, Craig A. Grimes, Shihai Xu, Thomas J. LaTempa, Dongmei He |
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Rok vydání: | 2008 |
Předmět: | |
Zdroj: | Carbon. 46:1506-1508 |
ISSN: | 0008-6223 |
DOI: | 10.1016/j.carbon.2008.06.043 |
Popis: | A novel carbon fiber pretreatment is proposed. PAN-based carbon fibers are first anodized in a H3PO4 electrolyte to achieve an active surface, and then coated with Ti–B catalyst by immersion of the carbon fibers in a uniformly dispersed H3BO3-doped TiO2 sol. The as-treated carbon fibers are then graphitized at 2400 °C for 2 h. The effects of the anodization and the Ti–B catalyst on the graphitization are investigated. |
Databáze: | OpenAIRE |
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