N-heterocyclic compounds of phosphorus based ON N,N-disubstituted 9,10-phenanthrenediimines

Autor:	G. G. Kazakov, Vladimir K. Cherkasov, Roman V. Rumyantcev, Gleb A. Abakumov, Nikolay O. Druzhkov, Georgii K. Fukin
Rok vydání:	2019
Předmět:	Steric effects Metal Multidisciplinary Chemistry Radical Phosphorus visual_art visual_art.visual_art_medium chemistry.chemical_element Medicinal chemistry
Zdroj:	Доклады Академии наук. 489:368-372
ISSN:	0869-5652
DOI:	10.31857/s0869-56524894368-372
Popis:	N‑heterocyclic phospholes based on N,N-disubstituted 9,10-phenanthrenediimines were synthesized. Dimeric 1,3,2-diazaphospholes were obtained by reduction of 2-bromo diazaphospholes. In case phenanthrediimine with the most sterically hindrance, diphosphole can dissociate into phosphorus-centered radicals at record low temperatures (220 K) for this class. This behavior will allow the synthesis of new metal complexes and phosphorus-organic compounds under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3c81a907a14da6e6780794ce3383ad79 https://doi.org/10.31857/s0869-56524894368-372 Zobrazit plný text záznamu