Radiation-Chemical Synthesis of Perfluorinated Tetrafluoroethylene Telomers

Autor:	Yu. M. Shul'ga, P. P. Kushch, G. A. Kichigina, D. P. Kiryukhin
Rok vydání:	2021
Předmět:	Solvent chemistry.chemical_compound Polytetrafluoroethylene chemistry Telomerization Kinetics Polymer chemistry Molecule Infrared spectroscopy Tetrafluoroethylene Physical and Theoretical Chemistry Perfluoromethylcyclohexane
Zdroj:	High Energy Chemistry. 55:388-392
ISSN:	1608-3148 0018-1439
Popis:	The kinetics of radiation-initiated telomerization of tetrafluoroethylene in perfluoromethylcyclohexane and perfluoro-1,3-dimethylcyclohexane has been studied, and new perfluorinated telomers of tetrafluoroethylene have been obtained. A detailed study of IR absorption spectra of these telomers confirms the inclusion of fragments of solvent molecules in the composition of the resulting perfluorinated telomers, the absence of double C=C bonds in them, and their more amorphous structure. Analysis of the differences between the IR spectra of the telomers and polytetrafluoroethylene has also suggested that these telomers can be used to create superhydrophobic coatings.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3c711eb35f5e453cb8270045dd5cea0a https://doi.org/10.1134/s0018143921050064 Zobrazit plný text záznamu Plný text ve formátu PDF