A Polymeric Structure Containing Cu2Cl2 Units Bridged by 4,4‘-Bipyridine: (PPh3)2Cu2(μ-Cl)2(μ-4,4‘-bipyridine)
Autor: | Jian Lu, Tianyan Niu, Gerardo Crisci, Allan J. Jacobson |
---|---|
Rok vydání: | 1997 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 36:5140-5141 |
ISSN: | 1520-510X 0020-1669 |
Popis: | (4,4‘-Bipyridine)(triphenylphosphine)copper(I) chloride crystallizes in the triclinic space group P1 with a = 9.080(2) A, b = 9.295(2) A, c = 13.086(2) A, α = 105.64(1)°, β = 105.30(1)°, and γ = 94.91(2)°. The structure is build up by dimeric Cu2Cl2 units with bridging Cl anions, which are connected by a 4,4‘-bipyridine to form a chain structure. The triphenylphosphine ligand completes the coordination sphere around the copper atoms. |
Databáze: | OpenAIRE |
Externí odkaz: |