A Polymeric Structure Containing Cu2Cl2 Units Bridged by 4,4‘-Bipyridine: (PPh3)2Cu2(μ-Cl)2(μ-4,4‘-bipyridine)

Autor:	Jian Lu, Tianyan Niu, Gerardo Crisci, Allan J. Jacobson
Rok vydání:	1997
Předmět:	Coordination sphere Stereochemistry chemistry.chemical_element Triclinic crystal system Chloride Copper 4 4'-Bipyridine Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry medicine Physical and Theoretical Chemistry Triphenylphosphine medicine.drug
Zdroj:	Inorganic Chemistry. 36:5140-5141
ISSN:	1520-510X 0020-1669
Popis:	(4,4‘-Bipyridine)(triphenylphosphine)copper(I) chloride crystallizes in the triclinic space group P1 with a = 9.080(2) A, b = 9.295(2) A, c = 13.086(2) A, α = 105.64(1)°, β = 105.30(1)°, and γ = 94.91(2)°. The structure is build up by dimeric Cu2Cl2 units with bridging Cl anions, which are connected by a 4,4‘-bipyridine to form a chain structure. The triphenylphosphine ligand completes the coordination sphere around the copper atoms.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3c67f57cb1f74caf1d24783264e997ce https://doi.org/10.1021/ic9705507 Zobrazit plný text záznamu