Conversion of bio-char to CaC2 at low temperatures-morphology and kinetics
| Autor: | Zhenyu Liu, Renxing Wang, Qingya Liu, Zhengke Li, Xiaojin Guo |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Applied Mathematics General Chemical Engineering Kinetics 02 engineering and technology General Chemistry Activation energy Corncob 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Industrial and Manufacturing Engineering 0104 chemical sciences Reaction rate Chemical kinetics Chemical engineering Gravimetric analysis Particle size Char 0210 nano-technology |
| Zdroj: | Chemical Engineering Science. 192:516-525 |
| ISSN: | 0009-2509 |
| Popis: | The conversion of bio-char to CaC2 is a potential way to achieve the production of high-value-added chemicals from biomass. The unique properties of bio-char, such as its fine particles, high activity, and low ash content, provide a high reaction rate, low reaction temperature, and high CaC2 purity, which increase the feasibility of converting bio-char to CaC2. This work investigates the morphological behaviors of the solid reactants and the products, as well as the reaction kinetics, in terms of changes in activation energy and the particle size of the reactants. The experiments were carried out using a thermal gravimetric analyzer coupled with a mass spectrometer (TG-MS) at temperatures lower than 1700 °C using corncob char and CaO as the starting materials. The TG-MS data and kinetics modeling show that at temperatures of 1400–1700 °C, the reaction of corncob char and CaO with a particle size of 22–114 μm is predominantly under reaction control, but is slightly affected by the size of the reactants. During the course of the reaction, the reacting solids agglomerate via the formation of CaC2 without apparent melting. |
| Databáze: | OpenAIRE |
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