Syntheses of phosphorylcholine-substituted silsesquioxanes via thiol-ene ‘click’ reaction

Autor:	Su Jung Lee, Moon Gun Choi, Lei Liu, Philjae Kang, Myong Euy Lee
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Chemistry Phosphorylcholine Organic Chemistry Crystal structure Biochemistry Silsesquioxane chemistry.chemical_compound Drug Discovery Polymer chemistry Click chemistry Thiol Organic chemistry Ene reaction
Zdroj:	Tetrahedron Letters. 56:1562-1565
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2015.02.021
Popis:	Phosphorylcholine-substituted silsesquioxanes were synthesized via the UV-initiated thiol-ene ‘click’ reaction of octakis(3-mercaptopropyl)octasilsesquioxane (POSS-SH) with 2-methacryloyloxyethylphosphorylcholine or allylphosphorylcholine in mixed (DMF/MeOH) solvents, respectively. In addition, the crystal structures of POSS-SH and MPC were first determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3c30377e90553df85016d5efd3d94f64 https://doi.org/10.1016/j.tetlet.2015.02.021 Zobrazit plný text záznamu Full Text from ScienceDirect