Reaction of alkoxyhydroperoxides with metal salts alkyl halide preparation

Autor:	D. Van Der Steen, F. P. Van Lier, J. P. Ward, G. Cardinale, J.C. Grimmelikhuysen, J. A. M. Laan
Rok vydání:	1989
Předmět:	chemistry.chemical_classification Metal salts Organic Chemistry Halide Biochemistry Chloride chemistry.chemical_compound chemistry Drug Discovery Polymer chemistry medicine Ferric Organic chemistry Methanol Solvent effects Aliphatic compound Alkyl medicine.drug
Zdroj:	Tetrahedron. 45:5971-5978
ISSN:	0040-4020
Popis:	A synthesis is described of alkyl chlorides by reaction of methoxy hydroperoxides, prepared from 1-alkenes by ozonisation in methanol, with ferric chloride: RCHCH2→RCH(OOH)OCH3→R·→RC1. Yields of 1-chlorotetradecane were about 60%; those of other halides from 38 to 57%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3c2d21d66c20d1dd7281c9bbdac3dc99 https://doi.org/10.1016/s0040-4020(01)89123-7 Zobrazit plný text záznamu