Silicon-controlled oxidation of enol acetates to enones by electrochemical method

Autor: Lung Ching Lin, Jih Ru Hwu, Lu Lin Chueh, Shwu-Chen Tsay
Rok vydání: 1995
Předmět:
Zdroj: Tetrahedron Letters. 36:4093-4096
ISSN: 0040-4039
Popis: Anodic oxidation of β-silylcycloalkanone enol acetates 1a-d in glacial acetic acid containing tetraethylammonium p -toluenesulfonate afforded α,β-unsaturated β-silylcycloalkenones 2a-d exclusively in 81–95% yields. The silyl group in 1a-d directed the oxidation under electrochemical conditions.
Databáze: OpenAIRE