Silicon-controlled oxidation of enol acetates to enones by electrochemical method
Autor: | Lung Ching Lin, Jih Ru Hwu, Lu Lin Chueh, Shwu-Chen Tsay |
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Rok vydání: | 1995 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 36:4093-4096 |
ISSN: | 0040-4039 |
Popis: | Anodic oxidation of β-silylcycloalkanone enol acetates 1a-d in glacial acetic acid containing tetraethylammonium p -toluenesulfonate afforded α,β-unsaturated β-silylcycloalkenones 2a-d exclusively in 81–95% yields. The silyl group in 1a-d directed the oxidation under electrochemical conditions. |
Databáze: | OpenAIRE |
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