A migration process in some sulphur-substituted cycloheptatrienes studied using saturation transfer NMR

Autor:	Cornelis Erkelens, A. W. Zwaard, H. Kloosterziel
Rok vydání:	1983
Předmět:	Saturation transfer Chemistry Scientific method Physical chemistry Organic chemistry chemistry.chemical_element General Chemistry Sulfur
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 102:285-290
ISSN:	0165-0513
DOI:	10.1002/recl.19831020601
Popis:	Modified Forsen-Hoffman experiments (in the FT mode) show that, in 7-substituted cyclohepta-1,3,5-trienes benzenesulphonyl groups migrate in a random way, while phenylthio substituents show a specific 1,2-migration. Activation parameters for the migration process are given for a number of compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3c1feba276fb08c6ee1046b09450de2e https://doi.org/10.1002/recl.19831020601 Zobrazit plný text záznamu Plný text