Bifacial n-type silicon solar cells for upconversion applications
| Autor: | Jan Christoph Goldschmidt, Marc Rüdiger, Karl Krämer, Stefan Fischer, Martin Hermle, Aruna Ivaturi, Bryce S. Richards, Judith Frank |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Materials science
Silicon Renewable Energy Sustainability and the Environment business.industry Irradiance chemistry.chemical_element Phosphor Photon upconversion Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention Solar cell efficiency Planar Optics chemistry law Solar cell Optoelectronics Quantum efficiency business |
| Zdroj: | Solar Energy Materials and Solar Cells. 128:57-68 |
| ISSN: | 0927-0248 |
| DOI: | 10.1016/j.solmat.2014.05.014 |
| Popis: | Upconversion of sub-band-gap photons has the potential to increase the efficiency of solar cells significantly, but requires modification of the solar cells. In this paper, we present a calculation framework to assess the efficiency of a combined bifacial silicon solar cell upconverter device, which is then used to optimize the solar cell׳s front and rear side anti-reflection coatings. Our calculations show that an upconverter can increase the efficiency of an optimized solar cell by 3.0% relative. Subsequently, planar bifacial n -type silicon solar cells were fabricated with optimized anti-reflection coatings. An upconversion layer – containing the upconverter phosphor β -NaY 0.8 Er 0.2 F 4 embedded in the polymer perfluorocyclobutyl – was attached to the rear side of the solar cells and an external quantum efficiency arising from the upconversion of sub-band-gap photons of 1.69% was measured under 1508 nm monochromatic excitation with an irradiance of 1091 W/m 2 . This corresponds to a value of 0.15 (W/cm 2 ) −1 when normalized to the irradiance, constituting a five-fold increase compared to the previously best published normalized values that were achieved without optimized solar cells. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect