Pseudo-thermodynamic Parameters and Isotope Effects for Hydrolysis of a Series of Benzyl Chlorides in Water

Autor:	K. M. Koshy, R. E. Robertson, W. M. J. Strachan
Rok vydání:	1973
Předmět:	Solvent Hydrolysis Series (mathematics) Chemistry Organic Chemistry Enthalpy Kinetic isotope effect Inorganic chemistry General Chemistry Kinetic energy Temperature coefficient Catalysis Probable mechanism
Zdroj:	Canadian Journal of Chemistry. 51:2958-2962
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v73-440
Popis:	The temperature coefficient of the enthalpy of activation (ΔCp≠) for the hydrolysis of p-methyl, p-chloro and p-nitro benzyl chlorides have been determined, as well as α-deuterium isotope effects and kinetic solvent isotope effects. These results are discussed in terms of probable mechanism of hydrolysis in water.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3bf6bb8c5cd996567e3b15e38a5a6daf https://doi.org/10.1139/v73-440 Zobrazit plný text záznamu