Investigation of x-ray absorption k-spectra of chlorine in certain gases and molecular crystals

Autor:	V. M. Bertenev, A. P. Sadovskii, S. M. Blokhin
Rok vydání:	1971
Předmět:	genetic structures Solid-state X-ray Analytical chemistry chemistry.chemical_element General Chemistry Photochemistry Antibonding molecular orbital Spectral line Crystal Wavelength chemistry Chlorine sense organs Absorption (chemistry) Astrophysics::Galaxy Astrophysics
Zdroj:	Theoretical and Experimental Chemistry. 4:342-345
ISSN:	1573-935X 0040-5760
DOI:	10.1007/bf00524130
Popis:	The X-ray absorption K-spectra of chlorine were investigated in gaseous and solid Cl2, HCl, CCl4, and CHCl3. The first absorption peak does not undergo any changes on passing from the gaseous to the crystalline state, while the group of maxima with lower wavelength undergoes extremely substantial changes. It is proposed that in both the gas and the crystal the first maximum indicates a transition of the K-electron to an antibonding molecular orbital containing the 3px-orbital of chlorine, while the short-wavelength region for the solid state indicates the presence of wide energy bands in the crystal.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3bf47a956134feee608fcd9d8271d4db https://doi.org/10.1007/bf00524130 Zobrazit plný text záznamu Full text from SpringerLink