Structure of tetracene–argon and tetracene–krypton complexes from high resolution laser experiments at 450 nm

Autor:	Grzegorz Myszkiewicz, Izabela Szydłowska, W. Leo Meerts
Rok vydání:	2002
Předmět:	Argon Krypton General Physics and Astronomy Noble gas chemistry.chemical_element Laser Spectral line law.invention chemistry.chemical_compound Tetracene chemistry law Molecule Physical and Theoretical Chemistry Atomic physics Benzene
Zdroj:	Chemical Physics. 283:371-377
ISSN:	0301-0104
DOI:	10.1016/s0301-0104(02)00502-5
Popis:	The partly rotationally resolved spectra of tetracene–Ar and tetracene–Kr were revisited. In a previous study it was not possible to assign experimental spectra. The spectra were obtained from high resolution laser experiments around 450 nm. With state of the art fast computers and recently developed software and algorithms we succeeded in explaining the observed spectra. Rotational constants of the complexes are obtained from which the structure of the clusters are deduced. It is found that the noble gas is located above the middle of one of the central benzene rings of the tetracene molecule with distances to the plane of 3.42 and 3.65 A for Ar and Kr, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3bef2ff885ca59cbe3759473c450899a https://doi.org/10.1016/s0301-0104(02)00502-5 Zobrazit plný text záznamu Full Text from ScienceDirect