An approach to uncertainty estimation in determining polycyclic aromatic hydrocarbons in fuel-contaminated soils

Autor: Susana García-Alonso, F. J. García-Frutos, Rosa María Pérez-Pastor, A. García-Alvarez
Rok vydání: 2013
Předmět:
Zdroj: Toxicological & Environmental Chemistry. 95:26-37
ISSN: 1029-0486
0277-2248
DOI: 10.1080/02772248.2012.759576
Popis: An estimation of uncertainty contribution in the entire set of the analytical data of polycyclic aromatic hydrocarbons (PAHs) in soil during a full year is presented. The analyses were performed as part of a project devoted to the assessment of the natural attenuation of selected PAHs in agricultural soil contaminated by a fuel spill. In particular, we investigated the effect of natural attenuation on the PAH dissipation rate in plots of two types of scenarios in agricultural soils. One of them was previously affected by an accidental fuel spill 10 years ago, and the other one was non-affected. The major components for estimating uncertainty contributions have been evaluated based on intermediate precision from different levels of PAH mass fraction, sample locations, and long term data set. An analysis of variance (ANOVA) test was applied to the mass fractions of clean or blank soil sub-samples versus contaminated soil sub-samples for grouping comparable data. Variables of influence in this study were sit...
Databáze: OpenAIRE