Physical Organic Chemistry of Transition Metal Carbene Complexes. 7.1 Kinetics of Hydrolysis of (CO)5MC(OR)Ph (M = Cr, W; R = Me, Et) and (CO)5Cr(OMe)CHCHPh in Aqueous Acetonitrile

Autor: Francis X. Flores, Claude F. Bernasconi, Kevin W. Kittredge
Rok vydání: 1997
Předmět:
Zdroj: Journal of the American Chemical Society. 119:2103-2110
ISSN: 1520-5126
0002-7863
DOI: 10.1021/ja963617i
Popis: A study of the hydrolysis of (CO)5CrC(OMe)Ph (1a), (CO)5CrC(OEt)Ph (1b), (CO)5CrC(OMe)CHCHPh (1c), (CO)5WC(OMe)Ph (1d), and (CO)5WC(OEt)Ph (1e) in 50% MeCN−50% water (v/v) at 25 °C is reported. The...
Databáze: OpenAIRE