Photobleaching dynamics in small molecule vs. polymer organic photovoltaic blends with 1,7-bis-trifluoromethylfullerene
| Autor: | Logan E. Garner, Jason Pfeilsticker, Bryon W. Larson, Zbyslaw R. Owczarczyk, Vinila Nellissery Viswanathan, Olga V. Boltalina, Andrew J. Ferguson, Dylan H. Arias, Steven T. Christensen, Steven H. Strauss, Wade A. Braunecker, Praveen C. Ramamurthy, Colin P. Brook, Nikos Kopidakis |
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| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Materials science Photoluminescence Renewable Energy Sustainability and the Environment 02 engineering and technology General Chemistry Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Acceptor Photobleaching Small molecule 0104 chemical sciences chemistry.chemical_compound chemistry Thiophene General Materials Science Polymer blend 0210 nano-technology Photodegradation |
| Zdroj: | Journal of Materials Chemistry A. 6:4623-4628 |
| ISSN: | 2050-7496 2050-7488 |
| DOI: | 10.1039/c7ta10995d |
| Popis: | Two organic photovoltaic (OPV) donor materials (one polymer and one small molecule) are synthesized from the same constituent building blocks, namely thiophene units, cyclopentathiophene dione (CTD), and cyclopentadithiophene (CPDT). Photobleaching dynamics of these donor materials are then studied under white light illumination in air with blends of PC70BM and the bis-trifluoromethylfullerene 1,7-C60(CF3)2. For both the polymer and small molecule blends, C60(CF3)2 stabilizes the initial rate of photobleaching by a factor of 15 relative to PC70BM. However, once the small molecule:C60(CF3)2 blend bleaches to ∼80% of its initial optical density, the rate of photobleaching dramatically accelerates, which is not observed in the analogous polymer blend. We probe that phenomenon using time-resolved photoluminescence (TRPL) to measure PL quenching efficiencies at defined intervals during the photobleaching experiments. The data indicates the small molecule donor and C60(CF3)2 acceptor significantly de-mix with time, after which the blend begins to bleach at approximately the same rate as the neat donor sample. The work suggests that perfluoroalkylfullerenes have great potential to stabilize certain OPV active layers toward photodegradation, provided their morphology is stable. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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