High resolution rotational spectrum of FCO2 radical (extension to lower frequencies)

Autor:	Patrik Kania, Dagmar Babankova, Helge Willner, Stéphane Bailleux, Peter Musil, Štěpán Urban, Lucie Nová Stříteská, Helmut Beckers, Marie Šimečková, Zdeněk Zelinger, Lucie Kolesniková
Rok vydání:	2007
Předmět:	Physics Nuclear magnetic resonance Spectrometer Radical extension Rotational spectrum High resolution Physical and Theoretical Chemistry Atomic physics Ground state Spectroscopy Atomic and Molecular Physics and Optics Order of magnitude Microwave
Zdroj:	Journal of Molecular Spectroscopy. 243:292-295
ISSN:	0022-2852
DOI:	10.1016/j.jms.2007.02.017
Popis:	We have subsequently extended the measurement of the FC 16 O 2 radical to the lower frequency region, between 210 and 245 GHz with the recently developed Prague microwave spectrometer. About 60 new a-type R-branch transitions have been observed. Our present analysis enabled us to improve significantly the determination of the ground state constants: most of the parameters are now determined with higher precision up to an order of magnitude better than the previous study. In addition eight new constants could be determined or nearly determinable for the first time.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3bceaf3a415d1fb8616eef7e20cf65ab https://doi.org/10.1016/j.jms.2007.02.017 Zobrazit plný text záznamu Full Text from ScienceDirect