Reactions and crystal structures of heterodinuclear complexes R3Sn–M(CO)5 (M=Mn, Re) with some nitrogen ligands

Autor: Jing Li, Ning Yin, Wen Jing Peng, Yong Qiang Ma
Rok vydání: 2009
Předmět:
Zdroj: Chinese Chemical Letters. 20:465-468
ISSN: 1001-8417
Popis: Some reactions of R3SnM(CO)5 (M = Mn, Re) with CH3CN or pyridine were investigated to give complexes R3SnMn(CO)3LL′ or R3SnMn(CO)4L by a facile mild method. X-ray diffractions analyses show that, in contrast to the phosphine ligand occupying in axial position, nitrogen ligands occupy equatorial position.
Databáze: OpenAIRE