Adsorption and Migration Characteristics of Fluorine in Ash-Sluicing Water in Soils

Autor: Jin Songli, Wen Yanfeng, Jun Yan, Yingqi Wei, Hong Cai, Shuaifeng Wu, Jianzhang Xiao
Rok vydání: 2021
Předmět:
Zdroj: Science of Advanced Materials. 13:705-717
ISSN: 1947-2935
DOI: 10.1166/sam.2021.3957
Popis: The excessive fluorine content in ash-sluicing water has become one of the main environmental pollution problems in the thermal power generation industry. This study selected 5 representative soil types and used fluoride ions (F-) as the pollution control factor. The experimental results showed that the isotherms of the F- solutions prepared by deionized water (adsorbed by Jianbi clay and Fengrun sandy soil) and ash-sluicing water all conformed to the Langmuir isothermal adsorption equation. In terms of the F- solution prepared with ash-sluicing water, the adsorption isotherm of Tianshengqiao red clay conformed to the Langmuir isothermal adsorption equation; the adsorption isotherms of Beijing silty soil and Fen River loess conformed to the Henry isothermal adsorption equation. In terms of the maximum adsorption capacity, Tianshengqiao red clay > Jianbi clay > Beijing silty soil ? Fen River loess > Fengrun sandy soil. Through the experiments, we also found that the adsorption capacity decreased with increasing pH, and the pH buffering effects of the 5 soils, from high to low, were Tianshengqiao red clay > Jianbi clay > Beijing silty soil > Fen River loess > Fengrun sandy soil.
Databáze: OpenAIRE