Modes of complexation of non-substituted and substituted tetraazamacrocycles with Group 6 metal carbonyls. X-ray structure of [(permethylcyclam)Mo(CO)4 ]

Autor:	Hervé des Abbayes, Marek M. Kubicki, Jean-Claude Clément, Jean-Jacques Yaouanc, Véronique Patinec, Henri Handel
Rok vydání:	1995
Předmět:	Chemistry Organic Chemistry X-ray chemistry.chemical_element Metal carbonyl Tungsten Biochemistry Inorganic Chemistry Metal Crystallography Chromium Group (periodic table) Molybdenum visual_art Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 494:215-222
ISSN:	0022-328X
DOI:	10.1016/0022-328x(95)05406-f
Popis:	Reactions of complexation of tetraazamacrocycles L with Group 6 metal carbonyls [M(CO)6](M = Cr, Mo, or W) lead to [LM(CO)4], [LM(CO)3] or [LM(CO)2] entities, depending both on the size of the macrocycle and on the metal M. The structure of one representative complex [(permethylcyclam)Mo(CO)4] has been determined by X-ray diffraction (permethylcyclam: 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3b8b14bcc3ca46bfbe1e320846c0aac8 https://doi.org/10.1016/0022-328x(95)05406-f Zobrazit plný text záznamu Full Text from ScienceDirect