Recrystallization rates and processes in laser-amorphized poly(ethylene terephthalate)

Autor:	D. S. Dunn, Philip D. Richards, A. J. Ouderkirk, Eric Weitz
Rok vydání:	1993
Předmět:	Materials science Polymers and Plastics Kinetic model Organic Chemistry Kinetics Analytical chemistry Infrared spectroscopy Recrystallization (metallurgy) Laser law.invention Inorganic Chemistry law Polymer chemistry Materials Chemistry Crystallization Thin film Poly ethylene
Zdroj:	Macromolecules. 26:1254-1259
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma00058a009
Popis:	The recrystallization of laser-amorphized PET films has been followed in real time using IR spectroscopy. The laser amorphization process produces a unique set of conditions which makes possible a simplified interpretation of the data obtained during recrystallization of thin films. The observed data for the time dependence of the growth of recrystallized PET fits well to a kinetic model which includes both primary and secondary crystallization processes. Values obtained for the rate of the primary process agree well with literature values for spherulitic growth in PET, reaching a maximum rate of 94 nm/s at 170°C
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3b746a0af51749375347adae65a4ec78 https://doi.org/10.1021/ma00058a009 Zobrazit plný text záznamu